Reciprocating / Piston Compressor Mineral Oil (5 Litres) SCS

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Suitable for all brands of Air Compressor. Note this is Piston Oil.

For Screw Compressor Oil SEE> SCREW OIL LINK

Reciprocating Compressor Lubricant

You wouldn't use everyday oil in your reciprocating compressor any more than you would use regular-grade gasoline in a high performance car. That's why we created our 5L SCS Piston compressor lubricants. They're specifically formulated for reciprocating compressors, where the right lubricant is vital for efficient operation. SCS Oils eliminates the unnecessary additives found in multi-purpose lubricants. The result? A specially blended lubricant that's precisely formulated for efficient operation of your reciprocating compressor. For what its worth it is MADE in Australia.

 

5.3 Compressor oils

Compressor is a device that increases the pressure of air or any gaseous medium by decreasing their volume. Besides providing sufficient lubrication to mechanical components, compressor oils also involve in cooling, preventing corrosion and sealing the compression cylinder. Compressor oil requirements can vary depending on compressor type, properties of the medium being compressed and also the outlet pressures and temperatures. In general, all compressor oils are formulated to remain stable at high temperatures and high pressures during operation (Bart et al., 2013b).

The stability of compressor lubricants at elevated temperatures is a major issue. Compressors integrated in systems such as propane, isobutane and CO2 systems can result in discharge temperature around 215 °C. In these systems, synthetic-based compressor oils are often used as they can tolerate to maximum temperature range of about 250 °C. Adhvaryu and Erhan (2002) carried out a study in the effort to study the possibility of using vegetable oils as potential substitutes for high-temperature lubricants. Using PDSC, they found that epoxidized soybean oil (ESBO) added with 2.0 wt% antioxidant showed the highest thermal stability, with peak temperature of 264 °C. The deposit-forming tendency of ESBO was significantly reduced when compared to crude soybean oil as result of chemical modification. In a separate study, Ting and Chen (2011) found that the working efficiency analysis of air compressor using in-house formulated soybean oil mixtures was similar when compared to the conventional R 68 compressor oil.

For refrigeration compressor, the lubricant is expected to remain in the circulation system for the lifetime of the appliance, roughly 10–20 years. Nevertheless, oxidative stability is insignificant due to the lubricant is not exposed to the atmospheric oxygen and moisture. Instead, refrigeration lubricants should have good electrical insulation properties, able to resist decomposition induced by electric field and exhibit good low-temperature characteristics (Bart et al., 2013b). High dielectric strength enables the oil/refrigerant mixture to act as insulator, resisting electricity between motor windings and the body wall in a compressor. Good dielectric strength properties exhibited by vegetable oils is highlighted in Section 5.9.

Currently, there are only a few readily available compressor oils in market that claims to be made of renewable agricultural resources. Notable product lines include Vanguard Green by Vanair Inc (USA) and Bio-SynXtra™ Super FG by Renewable Lubricants (USA). They are available in multiple ISO viscosity grades and exceeds the DIN 51506 VDL requirements. These lubricants are intended for most compressors, i.e. stationary rotary compressors (screw and sliding vane), reciprocating compressors (water cooled and air-cooled), centrifugal compressors, and vacuum pumps.

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Gas Compression

David A. Simpson P.E., in Practical Onshore Gas Field Engineering, 2017

8.3.3 Compressor oil

The compressor oil is key successful screw compressor operation. The kinds of oil that we talk about are (1) mineral oil, (2) synthetic oil, and (3) semisynthetic oil. Each has strengths and weaknesses and each has a place where it excels.

Mineral oil. Least expensive, but it tends to be an excellent solvent for heavier hydrocarbons and when it takes on butanes and propanes (etc.) the characteristics of the oil changes until it stops performing per specifications. Mineral oil also tends to begin breaking down above 210°F (99°C), and when it has been exposed to a high-temperature transient, the oil does not return to original performance when cooled.

Table 8.5. Screw Compressor efficiency example data points

Empty Cell Empty Cell Press (psig) Temp (°F) Enthalpy (BTU/lbm)
Well-head 1 60.0 70 353.13
After suction controller 2 50.0 70 353.41
Compressor inlet 3 48.0 70 353.47
Out of compressor (gas) 4g 170.0 205 417.58
Out of coalescer (gas) 5 168.0 205 417.62
Out of cooler (gas) 6 160.0 120 374.74
After backpressure valve (gas) 7 160.0 120 374.74
Suction end of compressor (oil) C 48 192 7.309
Out of compressor (oil) 4o 170.0 205 13.528
Out of coalescer (oil) A 165.0 205 13,519
Out of oil cooler (oil) B 164.0 192 7.511
Out of oil pump (oil) D 200.0 192 7.576

Synthetic oil. Most expensive (usually by a good margin), but it tends to not act as a solvent for heavier hydrocarbons. Synthetic oils are very stable at high temperatures and values above 350°F (177°C) have been reported without permanent degradation. As always, you need to follow manufacturer’s recommendations for maximum temperature.

Semi-Synthetic oil. Mineral oil and synthetic oil can be blended to achieve specific intermediate properties. These blends are often very cost-effective.

Compatibility with water vapor. All of the oil types are significantly hydrophilic and have a prodigious capacity for absorbing water vapor. When the oil absorbs water vapor, it: (1) becomes more viscous (i.e., it is harder to pump), (2) loses lubricity (i.e., so you need to pump more), (3) increases surface tension (i.e., this allows bigger droplets to fail to coalesce in the outlet separator vessel), and (4) raises the oil level in the reservoir (increasing foaming and carryover).

There is simply no way that you can prevent the oil from absorbing the water vapor that is present in the gas, and removing the water vapor from the suction stream is very expensive. The only way to successfully operate an oil-flooded screw compressor in raw-gas service is to manage the temperature in the outlet separator vessel to cook the water vapor out of the gas. Fig. 8.11 shows an example of how a small change in discharge temperature can change the process. The inlet gas is saturated with water vapor and contains 5061 lbm/MMSCF (81 g/SCm). Inside the compressor, the gas is heated from 110°F (43.3°C) at 12 psia (82.7 kPaa) to 192°F (88.9°C) at 112 psia (772 kPaa).

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Figure 8.11. Screw compressor outlet water content.

At these discharge conditions, the gas can only hold 4225 lbm/MMSCF (70.9 g/SCm), so 826 lbm/MMSCF (13.2 g/SCm) stays in the oil, which represents a volume of nearly 100 gal (375 L) of water that remains in the oil for every MMSCF (28.3 kSCm) of gas. If the temperature out of the compressor is raised just 13°F (7.2°C), then the gas is able to carry more water vapor than what is present in the system, so it completes the cycle with no water left in the oil and the gas at 89% relative humidity.

8.3.3.1 Outlet temperature

A screw compressor compresses gas. The process can be assumed to be adiabatic. That means that Eq. (8.8) should have some role in predicting the discharge temperature. If we have a compressor that has a suction pressure of 12 psia (82.7 kPaa) at 80°F (26.7°C) and a discharge pressure of 112 psia (772 kPaa), Eq. (8.7) would predict the outlet temperature would be 405°F (207°C) with k=1.28. That temperature would be a very difficult problem for metallurgy and for operations in general. The injected oil must have a role to play in that temperature. First you should use Eq. (8.8) to calculate the heat of compression. Then you have to convert the flows to mass-flow rate. Eq. (8.15) is used to determine the thermal energy that the act of adiabatic compression added to the process.

(8.15)Qgas=m˙gas⋅cpGas⋅(TdischTheo−Tsuct)

The discharge temperature can now be determined using Eq. (8.16).

(8.16)Tdisch=Qgas+TsuctGas⋅m˙gas⋅cpGas+ToilIn⋅m˙oil⋅cpOilm˙gas⋅cpGas+m˙oil⋅cpOil

Example. A screw compressor has the conditions in Table 8.7.

Table 8.7. Screw compressor temperature example

Empty Cell Gas Both Oil
Atmospheric pressure   12 psia (82.7 kPaa)  
Suction pressure 0 psig (0 kPag)   40 psig (276 kPag)
Discharge pressure 100 psig (689 kPag)   100 psig (689 kPag)
Inlet temperature 110°F (43.3°C)   180°F (82.2°C)
Flow rate 300 MSCF/day (8.5 kSCm/day)   40 g pm (151 L pm)
Specific gravity 0.6   0.81
cp 0.527 BTU/lbm/R (2205 J/kg/K)   0.450 BTU/lbm/R (1884 J/kg/K)
k 1.28    

This data is used to calculate the temperature of the oil out of the compressor (Eq. (8.17)).

(8.17)m˙gas=qgas⋅ρgasStd=300,000SCF/day⋅0.046lbm/SCF=13,770lbm/daym˙oil=qoil⋅ρwater⋅SGoil=40gal/min⋅8.34lbm/gal⋅0.81⋅1440minday=389,000lbm/dayTdisch-gas=(110+460)(100+120+12)(1.28−1)/1.28=929RQgas=13,770lbm/day⋅(0.52669BTUlbm⋅R)⋅(929R−570R)=2.60×106BTU/day2.60×106BTU/day+570R⋅13,770lbm/day⋅0.52669BTUlbm⋅RTdisch=+640R⋅389111lbm/day⋅0.45BTUlbm⋅R13,770lbm/day⋅0.52669BTUlbm⋅R+389,000lbm/day⋅0.45BTUlbm⋅R=652R=192°F

This example is plotted on an extract of the McKetta–Wehe Chart in Fig. 8.11. In this example, the ability of the gas to hold water vapor at outlet conditions is less than its ability at inlet conditions, so 836 lbm/MMSCF (13 g/SCM) remain in the oil—increasing the volume of the oil reservoir by 30 gal/day (113 L/day).

8.3.3.2 Oil temperature control

The “standard” way to control oil temperature is shown in Fig. 8.12. In this common scheme, the 3-way “constant temperature valve” looks at the temperature into the screw and bypasses the cooler to try to maintain a constant input temperature. In the example in Table 8.7 the 3-way temperature control valve is set to maintain 180°F (82.2°C) into the process. You can see from the example, this setting (and the oil flow rate) result in a 12°F (6.6°C) ΔT, and 192°F ( 89°C) outlet temperature which causes considerable water to collect. Changing the set point would help for these exact conditions, but if gas-flow rate increases, or discharge pressure decreases, etc., it will no longer be correct. The long and the short of the story is that controlling the inlet temperature is a ineffective practice that has come to us from plant compressors (where, if you’ll recall, water-vapor in the gas is much lower) and really should have stayed there.

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Figure 8.12. Screw compressor “standard” temperature control.

The packagers of the first screw compressors that I deployed failed to understand field use to the extent that the 3-way valve was set for 140°F (60°C) into the screw and the oil flow rate was expecting about three compression ratios (we had 12 compression ratios) so the oil was flowing so quickly that temperature out of the compressor was 142°F (61.1°C) and we had a considerable number of serious issues and very high oil-replacement/replenishment costs.

These skids were so basic that they didn’t even have a temperature gauge anywhere on the compressor, let alone on the compressor outlet.

After many months of fighting with controlling the wrong thing, I realized that life gets easier if you control the right thing (I’ve always been a slow learner). The “right thing” is to control the temperature out of the compressor in the face of frequently changing conditions. In Fig. 8.13, there is a temperature sensor looking at the temperature out of the screw. Based on that temperature, the PLC controls (it goes through the following steps in sequence with a 2-minutes pause before going to the next step)

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Figure 8.13. Flooded screw compressor effective temperature control.

1.

Adjust the speed of the glycol pump (can be adjusted to a minimum, and then on the next time the PLC looks at the glycol pump it can be turned off).

2.

Adjust the setting on the thermostatic valve on the oil pump discharge (this valve can go fully shut, the orifice in the bypass is sized for required lubrication and minimum oil-injection).

3.

Adjust the speed of the fan (can go to a minimum, but not zero).

4.

Adjust the speed of the oil pump (can go to a minimum, but not zero).

5.

Repeat.

A group of skids designed to this temperature control scheme was able to run for 3 years with zero unscheduled downtime and nearly zero added oil. This skid had variable speed drives on all electric motors. Before this skid was designed, I was reluctant to set an electric-motor driven compressor on a well site because that puts the weakest link under someone else’s control—a hard concept for a well-site engineer. After reviewing the results of this compressor, I am prepared to set a genset to run site facilities with electric power. Genset’s combined with variable speed electric motors has a high capital cost, but low-operating cost and the cross-over happens in the first couple of years.

8.3.3.3 Oil pressure management

As mentioned above, plant machines historically do not have oil pumps, but rely on the differential pressure across the skid to move oil. This can work in steady-state operations, but well-site and gathering operations are rarely steady state. Experience has shown that field compressors without oil pumps will tend to be on the top of down-time lists and failure reports. On engine-driven compressors oil pumps can be run off the pony shaft. On electric skids the oil pump should have its own variable speed drive.

8.3.3.4 Coalescing element

We often call the big lump of steel on the backside of the skid a “coalescing filter.” It is not a filter. The coalescing elements look somewhat like filter elements, but they serve a different function. The coalescing element is intended to force small droplets (that are buoyant in the gas stream) to crash into other droplets and coalesce into larger drops that are not buoyant in the gas. As is normal with any piece of equipment, there is a range where they are more effective. It is recommended to try to get the same magnitude of velocity in a coalescing element as the target velocity for in a separator mist pad (see Chapter 5: Well Site Equipment).

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Biolubricant product groups and technological applications

Jan C.J. Bart, ... Stefano Cavallaro, in Biolubricants, 2013

12.7 Compressor oils

Compressors decrease the volume and increase the pressure of air or any gaseous medium in one or more stages and thus transfer energy to the medium. The main functions of compressor oils are to lubricate bearings, pistons, cylinders and valves, thus reducing friction and wear. The lubricant also plays a role in cooling, preventing corrosion, achieving sealing of the compression chambers, and minimising viscosity dilution and reactions with process gases. Compressor oil requirements can vary substantially. Requirements depend on compressor type, the properties of the gas being compressed and discharge pressures and temperatures. A significant portion of compressor oils have a synthetic base. Universal lubrication requirements for compressor oils include:

low flammability;

oxidation resistance;

thermal stability;

viscosity retention;

AW capabilities;

corrosion prevention;

good demulsibility.

Few lubrication challenges are more difficult than creating an ideal oil for air compressors, particularly for the rotary screw air compressor. The compression process creates high temperatures and the oil, either in thin film or small droplets, intimately mixes with hot air. This mixture creates severe oxidation conditions, promoting rapid degradation of the oil. Consequently, compressor oil needs to be highly stable in the presence of air and water (i.e. exhibit oxidative and hydrolytic stability), provide excellent rust protection, separate easily from air and water, and be biodegradable for easy disposal. Present lubricant options range from traditional mineral oils to synthetic lubricants and more recently to POEs [157,158]. In severe operating conditions synthetic base stocks (typically PAO or mPAO with a solvent co-base stock such as an ester or alkylated naphthalene to improve additive solvency and seal capability) present a wide range of potential benefits, namely: (i) higher thermal and oxidative stability; (ii) higher VI and lower PP; (iii) potential for energy savings; (iv) enhanced wear protection and cleanliness; and (v) enhanced safety. In rotary air compressors modern fully synthetic oils can extend oil life up to 8000 h compared with 1000–2000 h for mineral oils.

Compressors are manufactured in several types and for a variety of purposes. It is possible to differentiate between air and gas compressors, vacuum pumps and refrigerant compressors. Vacuum pump lubrication requires synthetic oils with low vapour pressure (mostly synthetic ester oils). Enormous stress exerted onto the oil resulting from the high temperatures created when the medium is compressed may cause oxidation and favour deposit formation. Lubricating requirements vary considerably with the type of compressor, the pressures involved, the outlet temperature and gas being compressed. Most compressed air systems operate between 100 and 125 psig. Although air and gas compressors are mechanically similar, the main difference is in the effect of the gas on the lubricant and the compressor components. Compressors whose chambers are lubricated pose particular safety problems if air or aggressive gases contact the lubricant. Aggressive gases from the surroundings can influence the performance of the lubricant in an extremely negative way. The selection criteria for oils for various compressor types differ also greatly in relation to special demands. The latter include low foaming, excellent air release and good demulsibility (separation) of condensed water. Refrigeration and air conditioning compressors also require special consideration because of the recirculation of the refrigerant and mixing with the lubricant. If the medium to be extracted is not air, but a refrigerant, a compatible refrigeration oil should be used. The requirements for lubricants suitable for different types of compressors are given by Johnson [159]. For another detailed overview of compressor oils, see ref. [160].

A wide range of lube oils is available for use in compressors (Table 12.24). Lubricants commonly used are mineral oils (for normal and medium working conditions), hydrocracked oils (for medium to severe working conditions), and diester, polyester, PAG- or PAO-based lubricants (for very severe operating conditions). White oils are used as low-density polyethylene (LDPE) compressor oils. Water resistance, thermal stability, long life, resistance to oxidation and resistance to absorption of process gases are important characteristics. The lube’s usable lifespan can be reduced considerably by contaminants. Compressor lube oils are formulated to work well and remain stable at high temperatures and pressures. Hydrotreated mineral oils are used for their low gas solubility (1–5%). Synthetic compressor lubricants (PAO, PAG) are used depending on the process and how much gas is present. Petro-Canada Lubricants, Inc. (Mississauga, ON) has recently introduced a synthetic PAO-based Purity™ FG Compressor Fluid for food-grade applications (NSF H1) that protects against wear, oxidation, rust and corrosion. The product’s ASTM D 2272 resistance to oxidation (RPVOT, 4554 min) compares favourably with that of competitive synthetic products (1129–2364 min). PAG oils, which do not readily absorb gases, are used in applications where process gases are compressed. Mobile compressors are often lubricated with monograde engine oil (SAE 20 to 40). Because of explosion hazards, oxygen compressors require inert lubricants based on (extremely expensive) perfluoroether oils. Screw compressors require lubricants of moderate viscosity (ISO VG 46 or 68) with excellent oxidation stability and mild/high AW/EP performance; biodegradable polyol ester base oils qualify. Rotary piston compressors are lubricated by total-loss systems or by direct oil injection. SOILCY, an EU-sponsored sustainable compressor oil programme (FP6), has optimised the life cycle of an environmentally friendly polyglycerol ester-based compressor oil derived from the renewable resource glycerol (as a by-product of biodiesel).

Table 12.24. Overview of compressor oil types

Oil typea Type of compressor
Piston Screw Turbo
MO + +  
PAO + +  
Diester +    
HC   +  
POE   +  
TDL     +
Synthetic     +
a
MO, mineral oil; PAO, poly-α-olefin; HC, hydrocracked oil (so-called Group III oils); POE, biodegradable polyol esters; TDL, turbine oils.

Most of the common heat applications in pulp and paper, polymer, textile, agricultural and food industries require heating up to 140 °C, but some food drying and petrochemical processes require temperatures above 200 °C. A theoretical analysis of subcritical/transcritical heat pumps using natural refrigerants for high-temperature heating applications has been reported [161].

Environmentally benign natural refrigerants such as carbon dioxide, ammonia, propane, butane, isobutane and propylene may be used for heat pump applications [162]. Ammonia-based high-temperature heat pumps require special types of cooling and lubrication systems that are cost effective.

The stability of compressor lubricants at high temperatures is a major issue for heat pumps employed in high-temperature heating. Discharge temperature in case of propane, isobutane and CO2 systems (below 215 °C) does not pose any serious problem. Several lubricants are available for use up to a maximum temperature range of about 250 °C [163–165]. The synthetic lubricants for CO2 compressors, PAG, POE, PVE (polyvinyl ether) and PC (polycarbonate) have been tested for a maximum temperature of 220 °C [166]. The problem of high discharge temperature is very serious for an ammonia compressor, both for cooling and lubrication. Adequate cooling is required to increase compressor life. Adhvaryu and Erhan [167] proposed epoxidised soybean oil (ESO) as a potential high-temperature lubricant. Lubrication Technology, Inc. (LTI; Franklin Furnace, OH) manufactures high-technology synthetic lubricants based on perfluoropolyethers (PFPE), fluorinated polysiloxanes, esters, PAOs and hydrocarbon co-oligomers under the tradename CHRISTO-LUBE®, which cover a wide range of operating temperatures (from − 96 °C to + 288 °C) for demanding conditions [168]. Also Krytox fluorinated lubricants (operating range up to 426 °C) [169] may be employed in high-temperature applications.

Branched synthetic polyol ester base stocks can be used in the formulation of biodegradable compressor oils together with selected lubricant additives (oxidation inhibitors, additive solubilisers, rust inhibitors/metal passivators, demulsifying agents and AW agents) [6]. A typical biodegradable compressor oil contains 80–99% base stock, 1–15% solvent, with the remainder comprising the additive package. For additives in (PAO-based) compressor oils, see also ref. [170].

In compressors, lube oil is used to seal the compressor from gas leaks, lubricate moving parts and manage temperature during operation. The condition of the lubricant oil is a critical factor in extending a compressor’s bearing life and overall reliability. Hydrocarbons such as ethane and propane are easily soluble in mineral oil. This causes the viscosity of the lubricating oil to fall if mineral oil-based products are used. Ester- or polyglycol-based lubricants with lower hydrocarbon solubility are then recommended. Many factors can affect lube viscosity of a compressor, including oxidation, temperature changes, dilution, contamination and bubble formation. When a lubricant oil is diluted or comes in contact with vapours of methane or light hydrocarbons, the viscosity may break down quickly and unpredictably, increasing the risk of equipment failure. Compressor failure in a single part of a refinery determines important losses in production and revenues. Real-time in-line monitoring of lube viscosity in critical compressors, rather than monthly external lab testing, is the best and most costeffective way to avoid such costly failures [171]. Viscosity also plays a role in energy efficiency; demand for more efficient compressors is driving the use of lower-viscosity lubricants.

12.7.1 Refrigeration compressor lubricants

Refrigeration compressors deserve special mention in lubricant technology. Refrigerator oils are used in refrigerators, air conditioners, dehumidifiers, cold-storage chests, freezers, automatic vending machines, cooling units in chemical plants, etc., serving as a hydraulic control and functional fluid. In a domestic refrigerator or freezer compressor, motor bearings require lubrication. Refrigeration oils should help to ensure that the compressor and system components receive the proper lubrication for years of trouble-free operation. Since motor and compressor are sealed inside the refrigeration circuit, the lubricant cannot be changed for the lifetime of the appliance, typically 10–20 years. The lubricant is not exposed to atmospheric oxygen and water; consequently, oxidative and hydrolytic stability are of less importance than thermal stability. Refrigeration lubricants must have very good electrical insulation properties, must be stable to electrically induced decomposition and exhibit very good low-temperature fluidity characteristics with no tendency to deposition of waxes. High dielectric strength allows the oil/refrigerant mixture to serve as an insulator between the motor windings and the body in a compressor. The requirements of today’s refrigeration and air conditioning compressor lubricants are complex (see Table 12.25).

Table 12.25. General requirements for refrigeration lubricants

Lubricity properties

Excellent thermal stability

Superior low-temperature performancea

High chemical stability

Compatibility with refrigerantsb

Compatibility with polymeric materialsc and other materials of construction

Compatibility with other refrigeration oilsd

Controlled viscosity

High VI

Long service life

Freedom from moisture

High dielectric strength

Low energy consumption

a
Much lower PP than mineral oils.
b
Typically CFCs, HCFCs, HFCs, CO2, hydrocarbons, ammonia.
c
Typically BR, NR, NBR, HNBR, nylon-6,6, Teflon, EPDM, Neoprene, etc.
d
For retrofitting.

The principal functions of refrigeration oils are lubrication of pistons or rotors, sealing of valves and dissipation of heat. High-quality refrigeration oils are required in view of the longevity expected of such compressors, interaction with other substances and low and high temperatures. A mixture of lubricant and air-conditioning fluid must have sufficient lubricating properties to protect the air-conditioning pump, but should not be aggressive towards materials making up the system. Refrigeration oils should maintain high film strength even when diluted with refrigerant. High chemical stability minimises the reaction with refrigerants and other materials (e.g. elastomers) that are part of the system. Important factors are the lubricity of the refrigeration oil, interaction with the refrigerant, evaporation behaviour, solubility and mixture behaviour. Refrigerants and lubricants should be fully miscible and have high mutual solubility (at all temperatures that the system will experience), as in use of hydrofluorocarbon (HFC) refrigerants and POE lubricants. Lubricants with a thermal stability of > 175 °C generally work well in refrigeration systems. Ultra-low temperature refrigerants (as low as − 100 °C) require specialty lubricants (e.g. EMKARATE RL ‘H’). Obviously, for such applications all the components of the lubricant, including additives, need good solubility and low-temperature flow characteristics.

The most important parameter for determining the lubricity of oils or oil–refrigerant mixtures is viscosity. Selection of an optimum refrigeration oil depends on the specifications of the compressor, the system as a whole and the refrigerant. Refrigeration lubricants must have a wide variety of viscosities to achieve optimal effectiveness in the many different types of refrigeration equipment. For conventional home refrigerators, equipped with low power compressors, lubricants with relatively low viscosities at normal operating temperatures are generally satisfactory. Low-viscosity lubricants are preferred for economy of operation. By contrast, automobile air-conditioners and industrial refrigeration systems require relatively higher viscosity lubricants by reason of the more extreme conditions of operation. A high VI is an indication that their effective viscosity will not change drastically with the wide swings in temperature seen by most typical refrigeration and air conditioning systems. This means that energy consumption will be minimised at low temperatures and lubrication will be maximised at elevated temperatures.

Moisture can enter the refrigeration systems by improper evacuation of the system, system leaks, system components, improper handling of the refrigerant or of the lubricants. The moisture content for refrigeration lubricants should be < 100 ppm. Hygroscopicity of refrigeration lubricants ranks (in descending order) as PAGs > PVEs > POEs > alkyl benzenes (ABs) > mineral oils. The rate at which POEs pick up moisture is dependent on temperature, relative humidity, exposure time, and relative surface area. PAG lubricants are typically used in automotive applications and PVE is used sparingly in certain regions of the world.

Refrigeration oils differ according to the refrigerants being compressed (ASHRAE Standard 34–1992) [172]. A refrigeration lubricant must be miscible with the refrigerant gas. Modern refrigerants are halohydrocarbons (e.g. HFCs), such as HFC-134a and HFC-152a, as substitutes for the ozone layer destructive chlorofluorocarbons (CFCs), now in controlled use. Under the terms of the Montreal Protocol CFCs were phased out in 2000; HCFCs should be completely phased out in 2030. Hydrofluorocarbon (HFC) gases, which are currently the most widely used non-flammable, zero ozone depletion refrigerants, are relatively polar and not miscible with mineral oils.

Typical refrigerator oils are generally naphthenic or paraffinic mineral oils, ABs, polyglycolic oils, ester oils or their (additivated) mixtures with kinematic viscosity of 10–200 cSt at 40 °C. Mineral oils are still the most significant group of oils for traditional refrigeration compressors using ammonia along with CFCs and hydrochlorofluorocarbons (HCFCs), but ABs or PAOs are also being used. For instance, Glova [173] has disclosed a refrigeration lubricating oil composition based on branched-chain alkylbenzenes. These oils are not sufficiently soluble in the new chlorine-free substitute refrigerant mixtures (fluorocarbons (FCs) and HFCs) such as R 134a, R 404a and R 507. R 134a is currently the most commonly used new refrigerant. Modern synthetic refrigeration oils should not only have high lubricity, low hygroscopicity and high thermal and chemical stability, but also excellent compatibility with the alternative halohydrocarbons to ensure lubricant suitability. The tribological performance of POE and PVE synthetic lubricants operating with HFC-134a refrigerant has been reported [174]. Biodegradable POEs are the lubricants of choice for use with HFC gases [175].

Honeywell and DuPont are to produce a new eco-friendly refrigerant for use in car air conditioning systems. The refrigerant, dubbed HFO-1234yf (2,3,3,3-tetrafluoropropene), has a global warming potential (GWP) of 4; cf. GWP of 1 for CO2. The currently used refrigerant HFC-134a (1,1,1,2-tetrafluoroethane; main supplier: Mexichem) has a GWP of 1430, which is above the EU Mobile Air Conditioning Directive (2006/40/EC) that states that by 2011 all new vehicle models must use a refrigerant with a GWP below 150 [176]. Notice that HFC-23 (CHF3, fluoroform) is an extremely potent greenhouse gas with GWP of 14 800.

In the past, the widespread commercial use of chlorine-free refrigerant heat transfer fluids such as 1,1,1,2-tetrafluoroethane (formerly Klea 134a, ICI) has been hampered by the lack of commercially adequate lubricants. Examples of refrigeration oils that are miscible with HFCs include oxygencontaining compounds such as esters, ethers and carbonates. In particular, ester-based oils now constitute a most important product group. Various recent patents describe esters useful as refrigerator oils (see Table 12.26). Schnur [177] discloses an ester blend, including an ester based on NPG and/or PE and 2-ethylhexanoic acid. As the solubility of NPG and PE esters in non-chlorinated HFCs is often only fair, improved polyol-based esters are required. US Patent No. 6,582,621 to Sasaki et al. (to Nippon Mitsubishi Oil) [178] describes the development of mono- and dicarboxylic acid polyol esters with high insulating properties, whereas US Patent Appl. No. 2004/0046146 to Ankner et al. (to Neste Chemicals OY) [179] claims polyol esters comprising a sterically hindered diol esterified with mono- and dibasic carboxylic acids. In US Patent No. 6,831,045 [180] and US Patent No. 7,045,490 [181] Shimomura and Takigawa describe alicylic di- and polycarboxylic acid ester compounds. In US Patent No. 6,656,891 B1 (to Idemitsu Kosan Co.) Sakanoue et al. [184] disclose a refrigerating machine oil composition composed of a blend of PVE or POE with a PAG alkyl ether and an AB, suitable for HFC type, HC type, ether type, CO2 or ammonia-type refrigerants. Polyether-based lubricant oil compositions for refrigerators have also been disclosed by Enna et al. (to Asahi Glass Co.) [185] and Kaimai and Takahashi (to Japan Energy Corp.) [186]. Reflo™ is an inherently biodegradable ammonia-type refrigeration compressor oil (Petro-Canada Lubricants, Inc., Mississauga, ON).

Table 12.26. Selected refrigeration oil compositions

Lubricant base oil Refrigerant Reference
NPG/PE-2EH polyol ester blend HFC (R 134a) [177]
Mono- or dicarboxylic acid polyola ester; epoxy compound HFCs [178]
Diolb containing polyol esters HFCs [179]
Alicyclic dicarboxylic acid esters HFCs, CO2, hydrocarbons [180]
Alicyclic polycarboxylic acid esters HFCs, CO2, hydrocarbons [181]
Diesters, triesters HFCs (R 134a, R 410a) [182]
Polyol estersc HFCs (R 290, R 600a) [183]
a
EG, NPG, PE, TME, etc.
b
CHDM, 1,4-dimethylcyclohexane; ETHD, 2-ethyl-1,3-hexanediol.
c
EMKARATE RL™ product line.

Uniqema (formerly ICI)’s EMKARATE RL™ POE line is specifically designed for use with HFC and HCFC refrigerants and is widely accepted by major OEMs. These POE refrigeration lubricants cover a wide viscosity range from 7 cSt (35–40 SUS) to 220 cSt (1100 SUS). EMKARATE RL™ is designed specifically for use with environmentally friendly HFC refrigerants. The superior performance has been achieved with base fluids that are specifically formulated to deliver optimum performance with minimal additive levels. EMKARATE RL™ lubricants are compatible with all CFCs, HCFCs, HFCs, CO2 and hydrocarbons (e.g. R 290, R 600a) refrigerants, but not with ammonia (R 717) [183]. HFC refrigerants and the POE lubricant have both polar molecular structures, which attract polar water molecules. The solubility of water in HFCs, such as R 134a, is many times greater than in the CFCs they replace. POEs, such as EMKARATE RL™, are also considerably more hygroscopic than traditionally used mineral oils. Some physical properties of EMKARATE® RL 9HPlus are as follows: viscosity at 40/100 °C, 8.6/2.5 mm2/s; VI, 120; PP, − 49 °C; FP, 195 °C; AV, 0.01 mg KOH/g; no foaming [183].

Branched synthetic POEs have been used extensively in non-biodegradable applications, such as refrigeration lubricants, and have proven to be quite effective if more than 25% 3,5,5-trimethylhexanoic acid is incorporated into the molecule. However, trimethylhexanoic acid is not biodegradable (OECD 301B) and its incorporation into the lubricant base oil would drastically lower the biodegradation of the polyol ester due to the quaternary carbons contained therein. Also incorporation of trialkyl acetic acids (or neo acids) into POEs produces very useful refrigeration lubricants. Again, these acids do not biodegrade and cannot be used to produce POEs for biodegradable applications. POEs of all branched acids can be used in refrigeration oils, but they do not rapidly biodegrade. Although POEs made from linear C5 and C10 acids for refrigeration application are biodegradable under the Modified Sturm test, they would not be adequate as a lubricant in hydraulic or two-cycle engine applications because the viscosities would be too low and wear additives would be needed.

Recently, Chevron Corp. [182] has developed various diester and triester lubricating base oils for refrigeration application with molecular mass from 340 to 780 a.m.u. (Fig. 12.3) having kinematic viscosity of at least 3 cSt at 100 °C and PP below − 20 °C. Diester lubricants may be prepared according to Fig. 6.41 in which the C8–C16 olefin used is a reaction product of a Fischer–Tropsch process; the carboxylic acid can be derived from alcohols generated by Fischer–Tropsch and/or it can be a bio-derived FA [187]. Figure 12.4 shows the synthetic strategy for conversion of a mono-unsaturated fatty acid (MUFA; C10–C22) to a triester derivative. The demand for polyol esterbased synthetic refrigeration oils is increasing. It is essential to shield these ester oils from water in the compressor.

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12.3. Diester and triester refrigerator base oil compositions. After ref. [182].

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12.4. Synthetic strategy for conversion of oleic acid to triester derivatives. After ref. [182].

In subcritical CO2-based car air-conditioning systems special synthetic polyglycols (PAGs) or ester oils with AW/EP additives are to be used to guarantee the lifetime of the compressor under the severe conditions of the CO2 transcritical process.

Reducing electrical energy consumption through lubricant base fluid design and optimisation of lubricant performance are of considerable economic interest. Some 5–10% of the UK’s domestic electricity consumption is used to power refrigerators and freezers (up to 15% worldwide). A similar proportion of non-domestic power consumption is shared by industrial and commercial refrigeration and air conditioning [46].

Small appliance refrigeration compressors are designed to operate under conditions of hydrodynamic lubrication, where metal-to-metal contact is avoided by ensuring that a full-fluid film separates the surfaces. The energy required for shearing the entrained hydrodynamic film increases with the viscosity of the lubricant. Therefore, the energy requirement of an appliance compressor can be reduced by reducing the lubricant viscosity. However, if the lubricant viscosity is reduced too much, a full-fluid film is no longer ensured and the system will move into the boundary lubrication regime. Here, metal-to-metal contact occurs; wear reduces efficiency of the operation and limits the lifetime of the appliance. As friction coefficients in mixed and boundary lubrication greatly exceed those in the hydrodynamic regime, also increased frictional losses occur. Higher friction leads to overheating of the fluid and contacting surfaces, again compromising the expected life-time. Where possible, a periodic refrigerant analysis is important to detect and control contaminants (moisture, acid, particulate/solids, organic matter – sludge, wax, tars – and non-condensable gases) in the refrigerant, which can result in degradation/failure of the various components, and cause inefficient operation of the unit.

Structure–property relationships (see Table 10.15) have been used for optimisation of the energy efficiency of POEs in refrigeration lubrication applications [188]. Optimisation of POEs has permitted a gradual reduction in the industry standard lubricant viscosity from 18 cSt at 40 °C when polyol esters were first introduced to 10 cSt today. This translates into real benefits in energy consumption (about 10%) for a standard domestic refrigerator, as shown in Fig. 12.5. The new generation optimised POEs are also largely based on renewable materials and readily biodegradable (Fig. 12.6).

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12.5. Dependence of refrigerator energy consumption on lubricant viscosity. After ref. [188].

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12.6. Biodegradability by OECD 301B and percentage of renewable raw materials for various polyol ester refrigeration lubricant base fluids. After ref. [46].

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Lubrication

Stuart McGrory, in Plant Engineer's Handbook, 2001

52.13 Compressors

Compressors fall into two basic categories: positive displacement types, in which air is compressed by the 'squashing’ effect of moving components; and dynamic (turbo)-compressors, in which the high velocity of the moving air is converted into pressure. In some compressors, the oil lubricates only the bearings, and is not exposed to the air; in some, it serves an important cooling function; in some, it is in intimate contact with the oxidizing influence of hot air and with moisture condensed from the air. Clearly, there is no such thing as typical all-purpose compressor oil: each type subjects the lubricant to a particular set of conditions. In some cases good engine oil or turbine-quality oil is suitable, but in others, the lubricant must be special compressor oil (Figure 52.13).

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Figure 52.13. Compressor types

52.13.1 Quality and safety

Over the years, the progressive improvements in compressor lubricants have kept pace with developments in compressor technology, and modern oils make an impressive contribution to the performance and longevity of industrial compressors. More recently, a high proportion of research has been directed towards greater safety, most notably in respect of fires and explosions within compressors. For a long time the causes of such accidents were a matter of surmise, but it was noticed that the trouble was almost invariably associated with high delivery temperatures and heavy carbon deposits in delivery pipes. Ignition is caused by an exothermic (heat-releasing) oxidation reaction with the carbon deposit, which creates temperatures higher than the spontaneous ignition temperature of the absorbed oil.

Experience indicates that careful selection of base oils and anti-oxidation additives considerably reduce such deposits. Nevertheless, the use of top-class oil is no guarantee against trouble if maintenance is neglected. For complete safety, both the oil and the compressor system must enjoy high standards of care.

52.13.2 Specifications

The recommendations of the International Standards Organization (ISO) covering mineral-oil lubricants for reciprocating compressors are set out in ISO DP 6521, under the ISO-L-DAA and ISO-L-DAB classifications. These cover applications wherever air-discharge temperature are, respectively, below and above 160°C (329°F). For mineral-oil lubricants used in oil-flooded rotary-screw compressors the classifications ISOL-DAG and DAH cover applications where temperatures are, respectively, below 100°C (212°F) and in the 100–110°C range. For more severe applications, where synthetic lubricants might be used, the ISO-L-DAC and DAJ specifications cover both reciprocating and oil-flooded rotary-screw requirements.

For the general performance of compressor oils, there is DIN 51506. This specification defines several levels of performance, of which the most severe – carrying the code letters VD-L – relates to oils for use at air-discharge temperatures of up to 220°C (428°F).

The stringent requirements covering oxidation stability are defined by the test method DIN 51352, Part 2, known as the Pneurop Oxidation Test (POT). This test simulates the oxidizing effects of high temperature, intimate exposure to air, and the presence of iron oxide, which acts as catalyst – all factors highly conducive to the chemical breakdown of oil, and the consequent formation of deposits that can lead to fire and explosion.

Rotary-screw compressor mineral oils oxidation resistance is assessed in a modified Pneurop oxidation test using iron naphthenate catalyst at 120°C (250°F) for 1000 hours. This is known as the rotary-compressor oxidation test (ROCOT).

52.13.3 Oil characteristics

Reciprocating compressors

In piston-type compressors, the oil serves three functions in addition to the main one of lubricating the bearings and cylinders. It helps to seal the fine clearances around piston ringspiston rods and valves, and thus minimizes blow-by of air (which reduces efficiency and can cause overheating). It contributes to cooling by dissipating heat to the walls of the crankcase and it prevents corrosion that would otherwise be caused by moisture condensing from the compressed air.

In small single-acting compressors the oil to bearings and cylinders is splash-fed by flingers, dippers or rings, but the larger and more complex machines have force-feed lubrication systems, some of them augmented by splash-feed. The cylinders of a double-acting compressor cannot be splash lubricated, of course, because they are not open to the crankcase. Two lubricating systems are therefore necessary – one for the bearings and crosshead slides and one feeding oil directly into the cylinders. In some cases the same oil is used for both purposes, but the feed to the cylinders has to be carefully controlled, because under-lubrication leads to rapid wear and over-lubrication leads to a build-up of carbon deposits in cylinders and on valves. The number and position of cylinder-lubrication points varies according to the size and type of the compressor. Small cylinders may have a single point in the cylinder head, near the inlet valve; larger ones may have two or more. In each case, the sliding of the piston and the turbulence of the air spread the oil.

In the piston-type compressor the very thin oil thin has to lubricate the cylinder while it is exposed to the heat of the compressed air. Such conditions are highly conducive to oxidation in poor-quality oils, and may result in the formation of gummy deposits that settle in and around the piston-ring grooves and cause the rings to stick, thereby allowing blow-by to develop.

Rotary compressors – vane type

The lubrication system of vane-type compressors varies according to the size and output of the unit. Compressors in the small and ‘portable’ group have neither external cooling nor intercooling, because to effect all the necessary cooling the oil is injected copiously into the incoming air stream or directly into the compressor chamber. This method is known as flood lubrication, and the oil is usually cooled before being recirculated. The oil is carried out of the compression chamber by the air, so it has to be separated from the air; the receiver contains baffles that ‘knock out’ the droplets of oil, and they fall to the bottom of the receiver. Condensed water is subsequently separated from the oil in a strainer before the oil goes back into circulation.

Vane-type pumps of higher-output are water-jacketed and inter-cooled: the lubricant has virtually no cooling function so it is employed in far smaller quantities. In some units, the oil is fed only to the bearings, and the normal leakage lubricates the vanes and the casing. In others, it is fed through drillings in the rotor and perhaps directly into the casing. This, of course, is a total-loss lubrication technique, because the oil passes out with the discharged air.

As in reciprocating units, the oil has to lubricate while being subjected to the adverse influence of high temperature. The vanes impose severe demands on the oil's lubricating powers. At their tips, for example, high rubbing speeds are combined with heavy end-pressure against the casing.

Each time a vane is in the extended position (once per revolution) a severe bending load is being applied between it and the side of its slot. The oil must continue to lubricate between them, to allow the vane to slide freely. It must also resist formation of sticky deposits and varnish, which lead to restricted movement of the vanes and hence to blow-by and, in severe cases, to broken vanes.

Rotary compressors – screw type

The lubrication requirements for single-screw type compressors are not severe, but in oil-flooded rotary units, the oxidizing conditions are extremely severe because fine droplets of oil are mixed intimately with hot compressed air. In some screw-type air compressors, the rotors are gear driven and do not make contact. In others, one rotor drives the other. The heaviest contact loads occur where power is transmitted from the female to the male rotor: here the lubricant encounters physical conditions similar to those between mating gear teeth. This arduous combination of circumstances places a great demand on the chemical stability, and lubricating power, of the oil.

Other types

Of the remaining designs, only the liquid-piston type delivers pressures of the same order as those just mentioned. The lobe, centrifugal and axial-flow types are more accurately termed ‘blowers’, since they deliver air in large volumes at lower pressures. In all four cases only the ‘external’ parts – bearings, gears or both – require lubrication. Therefore, the oil is not called upon to withstand the severe service experienced in reciprocating and vane-type compressors. Where the compressor is coupled to a steam or gas turbine a common circulating oil system is employed. High standards of system cleanliness are necessary to avoid deposit formation in the compressor bearings.

Refrigeration compressors

The functions of a refrigerator compressor lubricant are the same as those of compressor lubricants in general. However, the close association between refrigerant and lubricant does impose certain additional demands on the oil. Oil is unavoidably carried into the circuit with refrigerant discharging from the compressor. In many installations, provision is made for removal of this oil. However, several refrigerants, including most of the halogen refrigerants, are miscible with oil and it is difficult to separate the oil that enters the system, which therefore circulates with the refrigerant. In either case the behavior of the oil in cold parts of the systems is important, and suitable lubricants have to have low pour point and low wax-forming characteristics.

Effects of contamination

The conditions imposed on oils by compressors – particularly by the piston type – are remarkably similar to those imposed by internal combustion engines. One major difference is, of course, that in a compressor no fuel or products of combustion are present to find their way into the oil. Other contaminants are broadly similar. Among these are moisture, airborne dirt, carbon and the products of the oil's oxidation. Unless steps are taken to combat them, all these pollutants have the effect of shortening the life of both the oil and the compressor, and may even lead to fires and explosions.

Oxidation

High temperature and exposure to hot air are two influences that favor the oxidation and carbonization of mineral oil. In a compressor, the oil presents a large surface area to hot air because it is churned and sprayed in a fine mist, so the oxidizing influences are very strong – especially in the high temperatures of the compressor chamber. The degree of oxidation is dependent mainly on temperature and the ability of the oil to resist, so the problem can be minimized by the correct selection of lubricant and by controlling operating factors.

In oxidizing, oil becomes thicker and it deposits carbon and gummy, resinous substances. These accumulate in the piston-ring grooves of reciprocating compressors and in the slots of vane-type units, and as a result, they restrict free movement of components and allow air leakage to develop. The deposits also settle in and around the valves of piston-type compressors, and prevent proper sealing.

When leakage develops, the output of compressed air is reduced, and overheating occurs due to the recompression of hot air and the inefficient operation of the compressor. This leads to abnormally high discharge temperatures. Higher temperature leads to increased oxidation and hence increased formation of deposits, so adequate cooling of compressors is very important.

Airborne dirt

In the context of industrial compressors, dust is a major consideration. Such compressors have a very high throughput of air, and even in apparently ‘clean’ atmospheres, the quantity of airborne dirt is sufficient to cause trouble if the compressor is not fitted with an air-intake filter. Many of the airborne particles in an industrial atmosphere are abrasive, and they cause accelerated rates of wear in any compressor with sliding components in the compressor chamber. The dirt passes into the oil, where it may accumulate and contribute very seriously to the carbon deposits in valves and outlet pipes. Another consideration is that dirt in oil is likely to act as a catalyst, thus encouraging oxidation.

Moisture

Condensation occurs in all compressors, and the effects are most prominent where cooling takes place – in intercoolers and air-receivers, which therefore have to be drained at frequent intervals. Normally the amount of moisture present in a compression chamber is not sufficient to affect lubrication, but relatively large quantities can have a serious effect on the lubrication of a compressor. Very wet conditions are likely to occur when the atmosphere is excessively humid, compression pressures are high, or the compressor is being overcooled.

During periods when the compressor is standing idle, the moisture condenses on cylinders walls and casings, and if the oil does not provide adequate protection, this leads to rusting. Rust may not be serious at first sight, and it is quickly removed by wiping action when the compressor is started, but the rust particles act as abrasives, and if they enter the crankcase oil they may have a catalytic effect and promote oxidation. In single-acting piston-type compressors, the crankcase oil is contaminated by the moisture.

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Seals

Michael Forsthoffer, in Forsthoffer's Component Condition Monitoring, 2019

Compressor Oil Seals

There are a number of different designs of oil seals for compressor, all of which essentially have the same key parameters to monitor for condition.

Figs. 6.5–6.7 show a few different types of oil seals found in compressors.

Fig. 6.5

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Fig. 6.5. Bushing seal.

Fig. 6.6

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Fig. 6.6. Elliott Iso-carbo seal.

(Courtesy of Elliott Co).

Fig. 6.7

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Fig. 6.7. Contacting oil seal.

(Courtesy of IMO Industries.)

All of these seals have a seal oil inlet at a differential pressure above the reference gas pressure; however the bushing seal (Fig. 6.5) uses a level control valve and an overhead seal oil tank to maintain a DP of approximately 5 psid (0.3 bar) and the seals in Figs. 6.6 and 6.7 utilize a DP control valve to maintain the differential pressure. This is because they are essentially both contacting type seals and can handle a higher DP. In all compressor oil seals, the leakage across the process seal combines with the process or buffer gas and goes to sour oil drainers at a normal rate of anywhere from 5 to 40 gal per day. The drainers separate some of the gas from the contaminated oil and return the oil to a degassing tank before entering the seal oil reservoir (usually the same as the lube oil reservoir). Leakage across the atmospheric side seal flows directly back to the reservoir, as it is not contaminated.

The key parameters to monitor include seal oil control valve position, sour oil leakage, and drainer level.

If level in the sour oil drainer is not present, you should immediately sniff the reservoir and take an oil sample to check for gas in the oil, as this could be a serious safety hazard. A spreadsheet will be available in Chapter 7 containing all the parameters to check on the Seal oil system. See Fig. 6.8 for a summary of parameters to check for a compressor oil seal.

Fig. 6.8

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Fig. 6.8. Parameters to monitor for compressor oil seals.

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Reliability and performance of direct-expansion ground-coupled heat pump systems: Issues and possible solutions

Demba Ndiaye, in Renewable and Sustainable Energy Reviews, 2016

4 Oil return to compressor

In a compressor, oil forms a thin film between moving parts, which reduces friction and wear, and may remove heat to help cool the compressor. Oil helps also to reduce noise from the compressor. Oils used in refrigeration applications can be categorized as mineral oils or synthetic oils (e.g. polyol esters). Refrigerants may be classified as completely miscible, partially miscible, or immiscible, according to their mutual solubility relationships with oils [23]. For example, ammonia, carbon dioxide, and R-410A among popular refrigerants are considered immiscible (very low miscibility) with mineral oils, whereas R-22 is considered partially miscible with mineral oils. In most refrigerant/oil solutions, partial miscibility occurs only up to a certain limit: the critical solution temperature (CST). Above the CST, complete miscibility occurs [23]. In a refrigeration system, some oil gets entrained with the refrigerant discharged from the compressor. The oil that circulates in the circuit impacts the heat transfers and pressure drops in the evaporator and in the condenser. To ensure proper lubrication of the compressor and maintain its life, the oil carried away must be returned to the compressor. Partial miscibility is often not a problem in the condenser; however, in the evaporator, the coldest part of the system, immiscibility or phase separation is very likely if the evaporation temperature is below the CST.

In a DX-GCHP, especially in heating mode where the evaporator is the GHE, it may be very difficult to ensure oil return to the compressor. For example, for vertical loops in heating mode, the oil may easily separate from the refrigerant and remain at the bottom of the U-tubes due to gravity.

To ensure oil return to the compressor in DX-GCHPs, there are various possible solutions. A first idea is to minimize oil entrainment to the refrigeration circuit by using the conventional oil separator (see [12,19]). However, whereas oil separators are highly efficient for immiscible refrigerant/oil solutions such as mineral oil in an ammonia system, they are not as effective for partially miscible solutions [24].

If a high proportion of oil gets entrained in the refrigeration circuit, an oil trap may be used. An oil trap, with a small U-shaped bend, may be located at the lowest point where the return refrigerant vapor tube first exits the GHE when the system is operated in the heating mode [25]. Wang et al. [13] suggest to place a circular bend at the middle of each tube to prevent reverse oil flow (Fig. 4). Their study is based on the heating mode; it is not known how that bend will impact the cooling mode.

Fig. 4

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Fig. 4. Circular bend for enhanced oil return to compressor (reproduced with permission from [13]).

Getting the oil up through suction risers requires attention to design and relatively high refrigerant velocities. Kesim et al. [24] propose a formula to determine the minimum average refrigerant flow velocity:

V̅ref,min=(agρoilDi1.250.1582aρrefνref0.25−0.402ρrefνref0.25Di)1/1.75+0.1a2gνoil(Di0.1582a−0.402Di)

where a is the oil thickness (m), g is the gravitational acceleration (m/s2), ρ is density (kg/m3), Di is the internal diameter of the pipe (m), and ν is kinematic viscosity (m2/s). For typical applications, the oil thickness can be taken as Di/50 [24]. Higher minimum velocities are required if the pipe diameter increases. The reader should bear in mind that lower pipe diameters tend to increase pressure drop and reduce the performance of the heat pump. Goulburn and Fearon [14] reported optimum velocities to ensure oil return while minimizing pressure drops of 4–10 m/s for R-12 systems. Minimum refrigerant velocities of 5 m/s in horizontal GHEs, and 7 m/s in vertical GHEs, have been reported by [26].

Finally, operating the heat pump from time to time for about ten minutes with full-load, even if not required by the heating load of the building, was found able to help alleviate the oil return issue [27].

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Screw Compressors

Eugene “Buddy” Broerman, ... Justin Hollingsworth, in Compression Machinery for Oil and Gas, 2019

Oil-Flooded Screw Compressors

Figs. 6.7 and 6.8 show sectional views of an oil-flooded screw compressor. In oil-flooded screw compressors, sometimes referred to as oil-injected or wet screw compressors, oil is injected directly into the rotor chamber continuously during operation. The oil is discharged with the gas into an oil separator vessel and then must be separated from the gas on the discharge side before being injected back into the compressor again. The injection oil serves several purposes:

Fig. 6.7

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Fig. 6.7. Oil-flooded screw main components.

Fig. 6.8

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Fig. 6.8. Oil-flooded screw main components—3D.

1.

It provides a lubricating film between the male and female rotors. Oil-flooded screw compressors do not have timing gears. Instead, one rotor drives the other through direct contact (with an oil film between the two rotors). The drive rotor refers to the rotor that is coupled to the motor, while the driven rotor refers to the rotor that is moved by the drive rotor. Most oil-flooded screw compressors are male-rotor drive, but many female-rotor drive machines are available as well.

2.

It carries away much of the heat of compression. This enables higher pressure ratios than are thermally possible in oil-free screw compressors (in which the compression power increases the gas temperature, and a small part of the heat of compression is absorbed by the casing and rotors).

3.

It fills the internal clearances, increasing volumetric efficiency. The volumetric efficiency of an oil-flooded screw compressor can be 10%–20% higher than a similar oil-free screw compressor.

4.

It continuously flushes away contamination that might enter the machine from the suction header.

There are no internal seals at the conveying chamber of an oil-flooded screw compressor—all of the internal components are in contact with the oil and the gas. Therefore, all of the compressor internals must be compatible with the oil and the gas, and also must be rated for the full range of operating pressures and temperatures. The only seal is at the driveshaft, typically an oil-purged mechanical seal, either single or double. When a single mechanical seal is used, the seal is usually fed by the common oil system. When higher safety requirements call for a double mechanical seal, it is typical for a separate oil system to be used for the driveshaft seal. This allows better control of the temperature, pressure, and flow of the oil to the seal, and also ensures that any oil leakage on the atmospheric side of the seal does not contain any process gas.

Capacity control is possible via an integral slide valve (refer to Fig. 6.9). The slide valve is located below the rotors and moves axially, actuated hydraulically by the oil system and a system of control valves. Since the slide valve is not truly a valve, it is more accurate and clear to use the terms “load” and “unload” rather than “open” and “close” when referring to its movement. Moving the slide valve toward the unloaded position opens a bypass area on the suction side of the machine, which reduces the volume flow of the machine. Moving the slide valve toward the loaded position closes this internal bypass area and increases the volume flow of the machine. With a single-acting slide valve configuration, the slide valve is moved toward the unloaded position via oil pressure, and is moved toward the loaded position via discharge pressure. Thus, a small pressure difference must exist between suction and discharge in order to move the slide valve toward the loaded position. With a double-acting slide valve, the movement toward loaded and unloaded positions is done by the oil system and is not dependent on discharge pressure.

Fig. 6.9

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Fig. 6.9. Slide valve function.

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Mechanical plant electrical services

In Electrical Systems and Equipment (Third Edition), 1992

11 Air compressors

11.1 General description of plant

Compressed air at various pressures and flow rates is produced by compressors, normally electrically-driven, to satisfy the requirements of control and instrumentation, dust plant jet-blowers and dust pumps, boiler soot-blowing, automatic boiler control, boiler blowdown, turbine forced cooling, breathing apparatus and reactor purging as appropriate to the type of power station.

The main building complex of a power station is served by two primary compressed air systems — ‘general services air’ and ‘control and instrument air’. Figures 10.38 and 10.39 show typical control and instrumentation and general service compressed air systems for a power station. The ‘general services’ system is designed for a flow rate of 0.4–1.0 m3/s at pressure of 7.2 bar, the ‘control and instrument air’ system for 0.2 m3/s at 8.5 bar. Certain plants remote from the main complex, such as those producing hydrogen and sodium hypochlorite, are provided with independent air compressor plant.

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FIG. 10.38. Control and instrumentation compressed air system

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FIG. 10.39. General service compressed air system

Control and instrumentation air system requirements are most stringent in respect of the quality of the compressed air produced and its integrity. A typical system consists of two or three 100% duty electrically-driven air compressors, each complete with air coolers and oil/water separators, feeding two independent air receivers and air dryer systems via a manifold.

A typical general services air system consists of two 50% duty electrically-driven air compressors, each complete with air coolers and oil/water separators, supplying a common air receiver.

11.2 Air compressor drive motors

The drives are usually squirrel-cage induction motors, suitable for direct-on-line starting on 11 kV, 3.3 kV or 415 V three-phase 50 Hz supplies, of totally-enclosed fan cooled construction, as described in Section 2.2 of this chapter. They drive the compressors through either V-belts or flexible couplings and gearboxes. The V-belts and flexible couplings protect the motor from shock loading and vibration.

11.3 Heaters

Heaters in compressed air driers and compressor oil sumps are either connected in balanced three-phase banks and supplied through electrically-held contactors at 415 V three-phase 50 Hz or, for ratings up to approximately 3.5 kW, at 240 V single-phase 50 Hz. Heaters are equipped with dual thermostats, one for normal temperature control and the other acting as a safety device in the event of failure of the control system. The latter is manually reset and initiates remote and local alarms to warn of failure.

11.4 Automatic and safety controls

The compressed air systems are designed to operate automatically, all operating conditions, such as air pressures and temperatures, being continuously monitored. Plant start-up, shutdown and duty selection are performed in the central control room and plant failure alarms are displayed there. Control panels situated local to the compressors house all the alarms, indications and controls necessary for the maintenance and local control of the plant.

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Sustainability of a non-edible vegetable oil based bio-lubricant for automotive applications: A review

Yashvir Singh, ... Surbhi Jain, in Process Safety and Environmental Protection, 2017

2.2.3 Applications

Automotive oils: Used in the automobile and transportation industry; examples are engine oils, transmission fluids, gear box oils, as well as brake and hydraulic fluids.

Industrial oils: Oils used for industrial purposes; examples are machine oils, compressor oils, metal-working fluid, and hydraulic oils.

Special oils: Oils used for special purposes according to specific operations; examples are process oils, white oils, and instrumental oils.

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Compressed air systems

Alireza Bahadori PhD, in Essentials of Oil and Gas Utilities, 2016

2.20 Air compressors

To ensure maximum reliability of the instrument air supply, at least two compressors should be installed. These should be driven by two different and independent utilities, eg, steam and electricity. Each compressor should be arranged for normal operation and for stand-by, and should be capable of supplying the designed quantity of instrument air, plus the required quantity of tool air (4.4), and, if applicable, the required quantity of regeneration air.

Where it is essential to have stand-by also if one of the two compressors is not operational, eg, because of repairs or maintenance, the installation of a third compressor should be considered.

The installation of more than two compressors may also be considered for other reasons, eg, where the fluctuations in air consumption are greater than the range of one compressor, or where purchasing and maintaining a number of compressors each with a relatively low capacity is more attractive than a (small) number of compressors each with relatively large capacity.

In any case, the total capacity of the compressors driven by the most reliable utility should be sufficient to supply the design quantity of instrument air.

Note: In addition to the aforementioned compressors for normal plant operation, an independent emergency air compressor may be required.

2.20.1 Compressor specification

The compressor should be of the dry type cylinder and should supply oil-free air, and be complete with non-return valves, intercoolersaftercoolers, condensate draining facilities, etc.

The compressors and their drives should satisfy the requirements for running equipment as specified by the user.

2.20.2 Compressor piping

The inlet of the compressors should be so located that the instrument air is free from toxic, obnoxious, or flammable gases, and is free from dust.

The inlet opening should be fitted with a wire mesh cage. The cage should be of adequate size to prevent flying papers, etc. from completely blocking the compressor inlet; the wire mesh should be adequate to prevent flying objects from entering the compressor and to prevent plugging by frost or hoar-frost.

Where the compressor inlet cannot be located in a completely dust-free area, consideration may be given to dust filters in the inlet piping.

To reduce the load on the air drier, the air from the compressors should be cooled to a temperature of 5–10°C above the cooling medium inlet temperature. Where the aftercoolers supplied as an integral part of the compressors are suspected of having only marginal capacity, the installation of additional aftercoolers should be considered.

2.20.3 Compressor controls

Each compressor should have the facilities for manual and automatic starting in the case of failure of the other compressor(s).

The automatic starting system should be so arranged that stopping of a compressor is only possible by manual control.

Automatic starting of the stand-by compressor(s) should be as quick as possible; in addition to an initiator on the piping downstream of the air drier. Initiators should be provided at each compressor discharge upstream of the non-return valve and/or on the compressor oil system. Starting of each stand-by compressor should be indicated by an alarm on the main panel.

The electric motor(s) should have local start/stop controls and be protected against repetitive starting. Electric controls supplied as integral parts of the compressor, as for oil filter, oil pump, oil heater, should be interlocked with the start/stop controls and should be located in a weatherproof housing on, or close to, the compressor.

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(PistonOil5L)

SKU PistonOil5L
Brand SCS
Shipping Weight 5.0000kg

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